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METALLURGICAL TECHNICAL GUIDE

Stainless Steel 904L (UNS N08904)

SS 904L is a high-alloy super-austenitic stainless steel engineered with 25% nickel, 4.5% molybdenum, and 1.5% copper. The copper addition imparts unique resistance to sulfuric, phosphoric, and organic acids, while the high nickel and molybdenum content provides outstanding immunity to chloride stress corrosion cracking.

Material Quick Reference

Material ClassificationSuper-Austenitic Stainless Steel (High Ni-Cr-Mo-Cu)
Pitting Resistance (PREN)34 - 36
Temperature Limits-50°C to +400°C
Governing SpecificationsASTM B677 (Pipe), ASTM B366 (Fittings), ASTM B649 (Forgings), ASME B31.3

Typical Engineering Applications

  • Sulfuric acid handling and concentration plants
  • Seawater heat exchangers and piping
  • Flue gas desulfurization (FGD) scrubbers
  • Fertilizer phosphoric acid synthesis loops

Chemical Environment & Corrosion Resistance

Exceptional resistance across the full concentration range of sulfuric acid up to 35°C, and resistant to warm brackish water.

Performance in Qatar's Coastal & Industrial Climate

Widely used in Mesaieed chemical plants and fertilizer complexes for sulfuric and phosphoric acid piping.

Welding & Fabrication Guidelines

Welded with matching ERNiCrMo-3 (Inconel 625) or matching 904L consumables under strict low heat input (< 1.0 kJ/mm).

Positive Material Identification (PMI) Requirements

XRF verification: 23–28% Ni, 19–23% Cr, 4–5% Mo, 1–2% Cu.

Key Advantages

  • Immune to chloride SCC in warm waters
  • Superior acid corrosion resistance vs 316L
  • Fully austenitic (non-magnetic)

Engineering Limitations

  • High cost compared to duplex alloys; lower mechanical yield strength than Duplex 2205
RAPID TECHNICAL ESTIMATION

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